It is possible to adjust the location of the upload button, by changing the position of the ly.img.upload library inside ui.elements.library.insert.entries - Example Code:
libraries: { insert: { entries: (defaultEntries) => { console.log({ defaultEntries }); const uploadLibraryIndex = defaultEntries.findIndex( ({ id }) => id === "ly.img.upload" ); const item = defaultEntries.splice(uploadLibraryIndex, 1)[0]; // remove the item from its current position and get a reference to it // Move it to position 3 defaultEntries.splice(3, 0, item); return defaultEntries; } } }